Effects of constant voltage on time evolution of propagating concentration polarization.

نویسندگان

  • Thomas A Zangle
  • Ali Mani
  • Juan G Santiago
چکیده

We extend the analytical theory of propagating concentration polarization (CP) to describe and compare the effects of constant-voltage versus constant-current conditions on the transient development of CP enrichment and depletion zones. We support our analysis with computational and experimental results. We find that at constant voltage, enrichment and depletion regions spread as t(1/2) as opposed to the previously observed t(1) scaling for constant current conditions. At low, constant voltages, the growth and propagation of CP zones can easily be misinterpreted as nonpropagating behavior.

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عنوان ژورنال:
  • Analytical chemistry

دوره 82 8  شماره 

صفحات  -

تاریخ انتشار 2010